Silica Gel | Desiccant, Moisture Absorber, Adsorbent

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Silica gel has been around since the 1640s, when it was little more than a scientific curiosity. During World War I, it was used to absorb vapors and gases from gas mask canisters. In 1918, Johns Hopkins University chemistry professor Walter A. Patrick patented a synthetic route for silica gel.

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Introduction to Silica Gel

Silica gel is an amorphous, porous silicon dioxide (silica) consisting of an irregular, three-dimensional framework of alternating silicon and oxygen atoms, with nanometer-scale voids and pores. These voids may contain water or other liquids, or they may be filled with gas or a vacuum. In the latter case, the material is more appropriately referred to as silica xerogel.

Silica xerogel has an average pore size of 2.4 nanometers and has a strong affinity for water molecules, making it widely used as a desiccant. It is hard and translucent, but much softer than bulk silica glass or quartz, and it remains hard even after being saturated with water.

Silica xerogel is typically sold as coarse granules or beads, several millimeters in diameter. Some granules may contain a small amount of an indicator that changes color when they absorb water. Small paper bags containing silica xerogel granules often carry a “Do Not Eat” warning and are commonly used in dry food packaging to absorb moisture that could cause food to spoil.

“Wet” silica gel, usually freshly prepared from an alkaline silicate solution, varies in consistency from a soft, clear gel similar to gelatin or agar to a hard solid (i.e., a water-absorbing xerogel). It is sometimes used in laboratory processes, for example, to inhibit convection in liquids or to prevent the settling of suspended particles.

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Properties

Silica gel that has absorbed water can be regenerated by heating it at 120°C for two hours.

Soaking silicic acid gel in a solution of cobalt chloride or ammonium chlorocobaltate ((NH₄)₂CoCl₄) and then drying and activating it produces color-changing silica gel, which can be used to indicate the degree of water absorption. This is because anhydrous cobalt chloride (CoCl₂) is blue, while cobalt chloride hexahydrate (CoCl₂·6H₂O) is red.

In daily life, silica gel is often found packaged in paper bags or bags made of semipermeable resin. It is used as a food or item desiccant to absorb moisture, control humidity, and prevent spoilage. Silica gel bags are generally labeled “Do Not Eat.” It can cause irritation to the respiratory and digestive systems, skin, and eyes. Furthermore, some color-changing silica gels contain humidity indicators such as cobalt chloride, which is a toxic substance and classified as an IARC Group II carcinogen, potentially causing cancer.

Types

  • Type A – Transparent particles with an approximate pore size of 2.5 nm. They offer drying and moisture-resistant properties and can be used as catalyst supports, adsorbents, separators, and pressure swing adsorbents.
  • Type B – Translucent white particles with a pore size of 4.5–7.0 nm. They are used as liquid adsorbents, desiccants, and fragrance carriers. They can also be used as catalyst carriers and cat litter.
  • Type C – Translucent particles with a microporous structure are used as a raw material for silica cat litter. After drying and sieving, they form macroporous silica gel, which can be used as a desiccant, adsorbent, and catalyst support.
  • Silica-alumina gel – Light yellow in color, chemically stable, flame retardant, and insoluble except in alkali or hydrofluoric acid. Its surface is polar and thermally stable, outperforming fine-porous silica gel.

Stabilized silica gel – Amorphous, microporous solid powder, non-toxic and flame retardant. It is used in beer grain brewing to improve taste, clarity, color, and foam, and remove non-microbial impurities.

What the Use of Silica Gel?

Is Silicone Toxic?

Silicone is a very stable polymer that withstands a wide range of temperatures and chemicals, so it’s considered relatively safe. Many experts and authorities consider silicone non-toxic and safe for contact with food and water. For example, Health Canada states that there are no known health hazards associated with the use of silicone cookware. Silicone rubber does not react with food or beverages and does not produce any hazardous fumes.

Silicone is non-toxic, non-reactive, and stable under normal use conditions. It reacts with hydrogen fluoride, fluorine, oxygen difluoride, chlorine trifluoride, strong acids, strong bases, and oxidizing agents. Silicone can irritate the respiratory tract and may irritate the digestive tract. Silica gel dust may irritate the skin and eyes, so precautions should be taken. Crystalline silica dust can cause silicosis, but synthetic amorphous silica is hardened and therefore does not cause silicosis. Additional hazards may arise if moisture indicators are added to silicone.

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References

Daghooghi-Mobarakeh H, Miner M, Wang L, et al. (2022). “Application of ultrasound in regeneration of silica gel for industrial gas drying processes”. Drying Technology.

Henisch H (1988). Crystals in Gels and Liesegang Rings. Cambridge: Cambridge University Press.

Silica Gel CAS 112926-00-8 | Look Chemical