The Manufacturer’s Guide to Fluorescent Brightener 220 (CAS 16470-24-9): Engineering, Synthesis, and Industrial Sourcing

Fluorescent Brightener 220 CAS 16470-24-9
Fluorescent Brightener 220 CAS 16470-24-9

Name: Fluorescent Brightener 220

CAS: 16470-24-9

Purity: 99%min

MOQ: 1KG

Directory Guidance on Fluorescent Brightener 220

Chemical Structure

Fluorescent Brightener 220

Product Background

In high-volume industrial manufacturing, achieving uniform, high-intensity whiteness in paper, textiles, and coatings requires absolute chemical precision. As a primary synthesis plant and global chemical supplier, our facility specializes in the large-scale production of Fluorescent Brightener 220 (CAS 16470-24-9), commercially recognized as Optical Brightening Agent (OBA) APC or Tetrasulfonated Stilbene Brightener.
Sourcing your optical brighteners directly from the manufacturing point guarantees chemical purity, mitigates supply chain volatility, and provides transparent access to primary analytical data. Below, our technical team breaks down the molecular characteristics, advanced synthesis pathways, and strict quality control standards maintained at our production plant.

Fundamental Technical Parameters

Fluorescent Brightener 220 is a tetrasulfonated derivative of diaminostilbene disulfonic acid (DAS). It functions via photoluminescence: absorbing invisible ultraviolet (UV) light in the 340–380 nm range and re-emitting it as visible blue light in the 400–440 nm spectrum. This blue emission effectively counteracts the natural yellowish tint of cellulose fibers and polymers.
Fundamental Technical Parameters:
  • Chemical Name: Tetrasodium 4,4′-bis[[4-[bis(2-hydroxyethyl)amino]-6-(4-sulfoanilino)-1,3,5-triazin-2-yl]amino]stilbene-2,2′-disulfonate
  • CAS Registry Number: 16470-24-9
  • Molecular Formula: C40H40N12Na4O14S4
  • Molecular Weight: 1165.04 g/mol
  • Ionic Character: Anionic
  • Primary Industrial Fields: Surface sizing and wet-end paper manufacturing, cotton textile dyeing, liquid detergents, and water-based coatings.

Advanced Synthesis & Refining Technology

Our factory implements a highly optimized, three-stage condensation reaction utilizing a continuous closed-loop system. This methodology ensures complete substitution reactions and drastically reduces hazardous waste generation.
[Cyanuric Chloride] + [DAS Acid] ──(1st Condensation)──> [Mono-condensate]
[Mono-condensate] + [Sulfanilic Acid] ──(2nd Condensation)──> [Di-condensate]
[Di-condensate] + [Diethanolamine (DEA)] ──(3rd Condensation)──> Fluorescent Brightener 220
The Production Phases:
  1. Primary Cyanuric Chloride Condensation: Cyanuric chloride is reacted with 4,4′-diaminostilbene-2,2′-disulfonated acid (DAS acid) at ice-cold temperatures (0–5°C) under strict pH control to yield the primary intermediate.
  2. Secondary Amine Substitution: Sulfanilic acid is introduced at moderate temperatures (30–40°C). Our computerized dosing systems maintain the pH profile within a narrow ±0.2 variance to prevent asymmetric side-reactions.
  3. Tertiary Alkanolamine Nucleophilic Substitution: Diethanolamine (DEA) is introduced at elevated temperatures (80–90°C) to displace the final chlorine atom, completing the tetrasulfonated structure.
  4. Desalination and Ultrafiltration: The crude liquid undergoes membrane ultrafiltration to remove inorganic salts (NaCl) and unreacted raw materials, ensuring a highly concentrated, low-viscosity final product.

Fluorescent Brightener 220 Uses:

In the textile industry, Fluorescent Brightener 220 is a busy person. If you walk into any textile factory, you are likely to encounter it in a dyeing vat, busy beautifying the fabric. It works very meticulously and can firmly adhere to fibers, whether it is natural fibers such as cotton and linen, or synthetic fibers such as polyester, it can handle them all. The most wonderful thing is that it not only makes white cloth whiter, but also acts as a “polisher” for light colored fabrics, making the colors look brighter and fuller. Nowadays, many manufacturers like to use it in combination with dyes, so that after one process, it can both color and whiten, saving time and effort. I heard that some particular manufacturers will adjust the amount of fabric added according to its thickness, using thinner ones less and thicker ones more. The results are quite reliable. And this thing is quite durable, even if you stay in a high-temperature dyeing tank for half a day, its performance will not be compromised. This makes the production process much more flexible, and it can handle both atmospheric and high-pressure dyeing. The most satisfying thing for manufacturers is its ability to save water and electricity for everyone – because of its strong effect, low usage, and reduced subsequent rinsing times, which is a real benefit.

The paper industry cannot do without Fluorescent Brightener 220. Think about it, pulp usually has a slight yellowish tone. If we rely solely on bleaching to whiten it, it will not only damage the fibers but also consume raw materials. At this point, it’s time for it to come on stage – adding it during the pulping stage or applying it to the surface during coating, and the paper instantly becomes snow-white and transparent. Especially for high-end photocopy paper and art magazine paper, which require high whiteness, its assistance is indispensable. Experienced teacher Fu Hui said that using whitening agents well is like applying a beauty filter to paper. Not only does it look comfortable, but the printing effect is also greatly improved. Nowadays, many paper mills use it as a secret weapon, after all, paper of the same quality can be sold for more money if its whiteness is one level higher. And it has a particularly good temper, can get along well with fillers and adhesives, and won’t easily precipitate or clump like some additives. If you go to the paper mill for a walk, you will see that the workers mix it into the pulp tank in a fixed proportion. The operation is simple and the effect is stable. No wonder everyone loves to use it.

The plastic industry has also gained a lot of experience in using Fluorescent Brightener 220. Plastic products are prone to yellowing, which is an old problem, especially those products that are left outdoors for a long time. But since it was introduced, this problem has become much easier – adding a little bit during granulation makes the injection molded product appear particularly white. Some old masters have made an interesting analogy: it’s like adding alkali to dough, and the dough immediately becomes snow-white. Nowadays, manufacturers of daily plastic products have gone out of their way and adjust the amount of additives according to the thickness of the product. If it is too thin, add less, and if it is too thick, add more. This not only saves costs but also ensures uniformity. What’s even more reassuring is that its heat resistance is indeed good, even if it rotates around in an injection molding machine at over 200 degrees, its performance is still stable. I have seen some manufacturers who pay attention to aging test, and their products are indeed more resistant to yellowing, which shows that they can not only whiten, but also help anti-aging, which is a benefit of buying one, getting one free.

Adding Fluorescent Brightener 220 to laundry powder and detergent is now very common. This thing is indeed smart. When washing clothes, it lurks in the water and quietly attaches itself when the clothes pass through the water. When the clothes are dried and worn out, they start working as soon as the sun shines, making white clothes whiter and lighter colored clothes less prone to graying. Housewives may not know that the secret to some so-called “brightening and brightening” laundry detergents lies here. And it works well with other ingredients in the laundry detergent and won’t come apart from each other. Many high-end detergents on the market now use this as a selling point, as visible effects are the most touching. To be honest, it is still its durability – the clothes have been washed more than ten times and the whitening effect is still there, which saves housewives a lot of worries.

Other industries also use Fluorescent Brightener 220 to demonstrate their own abilities. The paint factory regards it as a treasure because after adding it, the white paint appears whiter and the light colored paint is brighter; The printing factory found that the oil printed products with it were particularly clear; Even some skincare products add small amounts, using that optical principle to brighten the skin tone. Each industry adjusts its usage based on the characteristics of its own products. For example, cosmetics pay special attention to purity, while coatings place more emphasis on dispersibility. It seems that this thing is indeed a versatile one, it can glow and heat up wherever it is placed. If any new materials emerge in the future, it is estimated that they will be able to develop new applications, and this potential stock will become more and more valuable as we dig deeper.

Factory Capacity & Compliance Metrics

True authority is backed by infrastructure. Our chemical complex combines advanced manufacturing tech with international corporate responsibility standards.
  • Industrial Output: Our dedicated optical brightener facility operates continuous shifts, yielding over 12,000 metric tons of liquid and powder formulations annually.
  • Batch Uniformity: Utilizing DCS (Distributed Control Systems), every reaction parameter is logged electronically. This eliminates human error and guarantees that Batch 1 behaves identically to Batch 100.
  • Environmental & Supply Chain Certifications: Our manufacturing plant operates under ISO 9001:2015 (Quality Management), ISO 14001:2015 (Environmental Management), and ISO 45001:2018 (Occupational Health & Safety). We provide comprehensive regulatory support including full REACH compliance, SDS sheets, and heavy-metal testing profiles.

 

Related References:

  1. Chemicalbook
  2. Wikipedia

Fluorescent Brightener 220 Manufacturer & Supplier

As an experienced Fluorescent Brightener 220 manufacturer and supplier, Look Chemical is committed to producing and selling high quality products.

We cooperate and trade with 6000+ factories around the world, and our high-quality products and excellent services make us enjoy a high reputation internationally.

As Fluorescent Brightener 220 supplier, Look Chemical provides supply chain solutions to partners and customers in a wide range of industries. We offer competitive pricing and quality products.

If you have a demand for this product, please contact our company’s sales staff, we will provide you with a solution in the shortest time.

Empirical Laboratory Testing & Analytical Data

To verify the performance and stability of CAS 16470-24-9, our central Quality Control lab assesses every lot using High-Performance Liquid Chromatography (HPLC) and UV-Vis Spectrophotometry.
Standard Batch Analysis Spectrum (COA Metrics):
Performance ParameterFactory Specification LimitActual Lot Analysis ResultAnalytical Instrument / Method
AppearanceLight yellow uniform powder or liquidConformsVisual Inspection
Extinction Coefficient (E1% 1cm)420 ± 10 (Powder grade)423UV-Vis Spectrophotometer
Fluorescence Intensity100% ± 3% (vs. Standard Sample)101.5%Fluorometer
Moisture / Volatiles≤ 5.0% (For Powder)3.2%Moisture Balance (105°C)
Insoluble Matter (Water)≤ 0.2%0.04%Gravimetric Filtration
Free Amine Impurities≤ 0.5%0.12%Liquid Chromatography (HPLC)

Loading and Transportation

When formulating or processing materials at scale, raw material consistency dictates your operational efficiency. By partnering directly with our production facility, you secure factory-direct pricing, robust technical support, and transparent quality verification data.

To help our technical sales team prepare a tailored quote for your facility, please specify:
  • Which physical form is required for your setup: High-concentration dry powder or stabilized aqueous liquid?
  • Your anticipated monthly or annual tonnage requirements?
  • What specific industrial substrate (e.g., wet-end paper pulp, surface sizing starch, or textile fibers) you are brightening?
 

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